Eugenol (CAS N° 97-53-0)​

Photo credits: ScenTree SAS

Spicy > Warm Spices > Eugenol,spicy

Eugenol

2-methoxy-4-prop-2-enylphenol ; 4-allyl catechol-2-methyl ether ; 4-allyl guaiacol ; 4-allyl-1-hydroxy-2-methoxybenzene ; 1-hydroxy-2-methoxy-4-allyl benzene ; 1-hydroxy-2-methoxy-4-propenyl benzene ; 4-hydroxy-3-methoxy-1-allyl benzene ; 2-hydroxy-5-allylanisole ; 2-methoxy-4-(2-propen-1-yl)phenol ; 2-methoxy-4-allylphenol ; 2-methoxy-4-prop-2-enylphenol ; 2-methoxy-4,2-propen-1-ylphenol

Eugenol (CAS N° 97-53-0)​

Photo credits: ScenTree SAS

Company Ingredient Name ID Comments Naturality Certifications Purity Latin name Treated part Geographical origin MOQ
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Eugenol USP Natural 99.5% CL-502 Visit website Je me procure cet ingrédient Natural Certifications : Kasher Certifications : Halal Certifications : UEBT 99.5 Eugenia caryophyllus Clove Oil Indonesia 800 Kgs
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Eugenol Redistilled Natural 99%+ CL-501 Visit website Je me procure cet ingrédient Natural Certifications : Kasher Certifications : Halal Certifications : UEBT 99+ Eugenia caryophyllus Clove Oil Indonesia 800 Kgs
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EUGENOL M_0020312 Visit website Je me procure cet ingrédient Naturel - - - - -

Eugenol USP Natural 99.5%

ID : CL-502

Indonesia

Certifications : Certifications : Kasher Certifications : Halal Certifications : UEBT

Eugenol Redistilled Natural 99%+

ID : CL-501

Indonesia

Certifications : Certifications : Kasher Certifications : Halal Certifications : UEBT

EUGENOL

ID : M_0020312

Certifications :

Information Générales

General Presentation

  • CAS N° : 97-53-0

  • EINECS number : 202-589-1

  • FEMA number : 2467

  • FLAVIS number : 04.003

  • JECFA number : 1529

  • Appearance : Pinkish liquid

  • Density : 1,066

  • Volatility : Head/Heart

  • Price Range : €€

Physico-chemical properties

  • Molecular formula : C10H12O2

  • Molecular Weight : 164,2 g/mol

  • Log P : 2,7

  • Fusion Point : -11°C

  • Boiling Point : 253°C

  • Detection Threshold : 6 et 100 ppb (0,00001%)

  • Optical rotation : Donnée indisponible

  • Vapor pressure : Donnée indisponible

  • Refractive Index @20°C : Donnée indisponible

  • Acid Value : Donnée indisponible.

  • Flash Point : 112°C

Utilisation

Uses

Uses in perfumery :

Eugenol is used in ambery, vanillic, carnation, rose and spicy notes. Brings a spicy and vanillic touch to floral notes.

Year of discovery :

Data not available.

Natural availability :

Eugenol is present up to more than 90% in Clove Bud EO and in Cinnamon Leaf EO. These raw materials enable an easy extraction of Eugenol in its natural state.

Isomerism :

Isoeugenol is an isomer of Eugenol, as the double bond present on the two molecules is simply relocated from one molecule to another. However, its smell is fruity and less woody and vanillic. In addition, ortho and meta-Eugenol exist but are very little used in perfumery. For example, the smell of meta-Eugenol is quite similar to Eugenol, and has a strong aspect of carnation. Frambinone® and Styrallyl acetate are also constitutional isomers of Eugenol although they have a very different smell: fruity-raspberry for one, and rhubarb for the other.

Synthesis precursor :

Eugenol is a precursor to the synthesis of several compounds of olfactory interest. First of all, it allows to synthesize DihydroEugenol by catalytic hydrogenation. Isoeugenol can be synthesized from its isomer. Finally, an esterification or etherification of the alcohol function allows to obtain various compounds of interest.

Synthesis route :

Eugenol is often obtained by distilling natural raw materials. The essential oils (mainly Clove Bud EO) are placed in an alkaline medium, to isolate the non-phenolic compounds by distillation. After acidifying the medium at low temperature, Eugenol can be obtained by distillation too.

Utilisation

Regulations & IFRA

Allergens :

This ingredient does not contain any allergen.

IFRA 51th :

This ingredient is restricted by the 51th amendment

    IFRA's logo
  • Restriction type : RESTRICTION

  • Cause of restriction : DERMAL SENSITIZATION AND SYSTEMIC TOXICITY

  • Amendment : 51

Quantitative limit on the use :
Cat.1 Cat.2 Cat.3 Cat.4
Cat.5
A B C D
Cat.6
0,45 % 0,14 % 1,0 % 2,5 %
0,64 % 0,64 % 0,64 % 0,21 %
1,5 %
Cat.5
A B C D
Cat.6
0,64 % 0,64 % 0,64 % 0,21 %
1,5 %
Cat.7
A B
Cat.8 Cat.9
Cat.10
A B
Cat.11
A B
Cat.12
2,0 % 2,0 %
0,21 % 4,9 %
4,0 % 18 %
0,21 % 0,21 %
No restriction
Cat.10
A B
Cat.11
A B
Cat.12
4,0 % 18 %
0,21 % 0,21 %
No restriction

Annexe I :

Some regulated synthetic ingredients are found in nature and in certain proportions in natural ingredients. This presence in nature has to be taken into account when calculating limits of use recommended by the IFRA. In case you do not know these concentrations, you can use the ones estimated by the IFRA. Here they are :

List of regulated compounds contained in this ingredient
Ingredient Name Botanical Name CAS N° Estimated Concentration
Armoise vulgaris oil Artemisia vulgaris L. 68991-20-8 1
Basil oil, chemotype estragole Ocimum basilicum L. 8015-73-4 0,34
Basil oil, chemotype linalool Ocimum basilicum L. 8015-73-4 7,9
Basil oleoresin, chemotype estragole Ocimum basilicum L. 8015-73-4 0,2
Bay leaf, West Indian, oil Pimenta racemosa (Mill.) J.W. Moore 8006-78-8 51
Benzoin infusion, Sumatra Styrax paralleloneurum Perkins 0,001
Calamus oil Acorus calamus L. 8015-79-0 0,2
Cananga oil Cananga odorata (Lam.) Hook. f. & Thomson (forma macrophylla Steenis) 68606-83-7 0,4
Cinnamon bark CO2 extract Cinnamomum verum J. Presl syn. C. zeylanicum Blume 8015-91-6 2,5
Cinnamon bark oil Cinnamomum zeylanicum Blume 8015-91-6 2
Cinnamon leaf oil Cinnamomum zeylanicum Blume 8015-91-6 74
Cassia bark oil Cinnamomum cassia [L.] J. Presl syn. C. aromaticum Nees 8007-80-5 0,1
Cassia bark oleoresin Cinnamomum cassia [L.] J. Presl syn. C. aromaticum Nees 8007-80-5 0,02
Cassia oil Cinnamomum cassia [L.] J. Presl syn. C. aromaticum Nees 8007-80-5 0,1
Cascarilla bark oil Croton eleuteria (L.) W.Wright 8007-06-5 0,4
Cassie absolute Vachellia farnesiana (L.) Willd. 8023-82-3 0,06
Citron oil Citrus medica L. 68991-25-3 0,01
Champaca absolute Michelia champaca L. 8006-76-6 0,55
Cistus absolute Cistus ladaniferus L. 8016-26-0 0,06
Cistus oil Cistus ladaniferus L. 8016-26-0 0,4
Labdanum oil Cistus ladaniferus L. 8016-26-0 0,5
Citronella oil, Ceylon type Cymbopogon nardus (L.) Rendle 8000-29-1 0,2
Citronella oil, Java type Cymbopogon winterianus Jowitt 8000-29-1 0,9
Clove leaf oil terpenes Syzygium aromaticum (L.) Merr. & L.M.Perry 68917-29-3 0,77
Clove bud oil Syzygium aromaticum L. 8000-34-8 82
Clove bud oil terpenes Syzygium aromaticum (L.) Merr. & L.M.Perry 8000-34-8 27
Clove leaf oil Syzygium aromaticum L. 8000-34-8 85,3
Clove stem oil Syzygium aromaticum L. 8000-34-8 88
Turmeric oil Curcuma longa L. 8024-37-1 1
Tarragon oil Artemisia dracunculus L. 8016-88-4 0,6
Eucalyptus citriodora oil Corymbia citriodora (Hook.) K.D. Hill & L.A. Johnson 85203-56-1 0,12
Jasmine absolute Jasmium grandifloum L. 8022-96-6 1,53
Jasmine CO2 extract Jasmium grandifloum L. 8022-96-6 1
Jasmine concrete Jasminum grandiflorum L. 8022-96-6 1,53
Laurel leaf oil Laurus nobilis L 8007-48-5 1,33
Lemongrass oil, East Indian Cymbopogon flexuosus (Nees ex Steudel) Will. Watson 8007-02-1 0,08
Lemongrass oil, West Indian Cymbopogon citratus (DC) Stapf. 8007-02-1 0,2
Mace oil Myristica fragrans Houtt. 8007-12-3 0,7
Mace oleoresin Myristica fragrans Houtt. 8007-12-3 0,4
Mentha citrata oil Mentha citrata Ehrhart 68917-15-7 0,01
Mimosa absolute Acacia decurrens (Wendl.f.) Willd. 8031-03-6 0,02
Nutmeg oil Myristica fragrans Houtt. 8008-45-5 0,2
Nutmeg oleoresin Myristica fragrans Houtt. 8008-45-5 0,1
Carnation absolute Dianthus caryophyllus L. 8021-43-0 18
Origanum oil Thymus capitata (L.) Cav. 8007-11-2 0,08
Osmanthus absolute Osmanthus fragrans Lour. 68917-05-5 0,07
Osmanthus concrete Osmanthus fragrans Lour. 68917-05-5 0,06
Allspice oil Pimenta dioica (L.) Merr. 8006-77-7 69
Allspice oleoresin Pimenta officinalis Lindl. 8006-77-7 41,4
Pimenta leaf oil Pimenta officinalis Lindl. 8006-77-7 83
Pine Scotch, resinoid Pinus sylvestris L. 0,02
Rose oil Rosa x damascena Mill. 8007-01-0 1,14
Rose absolute Rosa x damascena Mill. 90106-38-0 0,65
Rose concrete Rosa x damascena Mill. 90106-38-0 1
Savory winter oil Satureja montana L. 3,32
Thyme absolute Thymus vulgaris L. 8007-46-3 0,12
Thyme oil, red Thymus vulgaris L. 8007-46-3 0,12
Thyme oil, white Thymus vulgaris L. 8007-46-3 0,1
Tuberose absolute Poliantes tuberosa L. 8024-05-3 0,5
Tuberose concrete Poliantes tuberosa L. 8024-05-3 0,48
Verbena absolute Lippia citriodora (L.) Kunth 8024-12-2 0,55
Ylang ylang oil I Cananga odorata (Lam.) Hook. f. &Thomson oil (forma genuine Steenis) 8006-81-3 0,58
Ylang ylang oil II Cananga odorata (Lam.) Hook. f. &Thomson oil (forma genuine Steenis) 8006-81-3 0,69
Ylang ylang oil III Cananga odorata (Lam.) Hook. f. &Thomson oil (forma genuine Steenis) 8006-81-3 0,45
Ylang, Ylang oil complete Cananga odorata (Lam.) Hook. f. &Thomson oil (forma genuine Steenis) 8006-81-3 0,31
Ylang, Ylang oil extra Cananga odorata (Lam.) Hook. f. &Thomson oil (forma genuine Steenis) 8006-81-3 0,34
Clove bud absolute Syzygium aromaticum (L.) Merr. & L.M.Perry 616-772-2 69,08
Genet absolute Spartium junceum L. 90131-21-8 0,02
Hyacinth absolute Hyacinthus orientalis L. 8023-94-7 0,2
Jasmine officinale absolute Jasminum officinale L. 8024-43-9 2
Lavandin grosso absolute Lavandula angustifolia Mill. x Lavandula latifolia Medik. 617-009-6 0,04
Ocatea cymbarum oil Ocotea cymbarum Kunth 68917-09-9 0,36
Sassafras bark oil Sassafras albidum (Nutt.) Nees 8006-80-2 0,36
Snakeroot oil Asarum canadense L. 8016-69-1 1
Ylang-ylang absolute Cananga odorata (Lam.) Hook.f.&Thomson forma genuina 0,5
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