(2E,6Z)-Nonadienol (CAS N° 28069-72-9)​

Photo credits: ScenTree SAS

Fruity > Juicy Fruits > Aquatic > Green > Metallic

(2E,6Z)-Nonadienol

Cucumber alcohol ; Violet leaf alcohol ; Alcool concombre ; Alcool feuille de violette ; (E)-2-(Z)-6-nonadienol ; (E,Z)-2,6-nonadienol ; Trans-2-cis-6-nonadien-1-ol ; E)-2-(Z)-6-nonadien-1-ol ; (E,Z)-2,6-nonadien-1-ol ; Nona-2,6-dienol ; Nona-2,6-dien-1-ol ; (Z,E)-nona-2,6-dienol ; (Z,E)-nona-2,6-dien-1-ol

(2E,6Z)-Nonadienol (CAS N° 28069-72-9)​

Photo credits: ScenTree SAS

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Information Générales

General Presentation

  • CAS N° : 28069-72-9

  • EINECS number : 248-816-8

  • FEMA number : 2780

  • FLAVIS number : 02.231

  • JECFA number : Donnée indisponible.

  • Appearance : Colorless liquid

  • Density : 0,87

  • Volatility : Head

  • Price Range : €€€€€

Physico-chemical properties

  • Molecular formula : C9H16O

  • Molecular Weight : 140,23 g/mol

  • Log P : 2,87

  • Fusion Point : Donnée indisponible.

  • Boiling Point : 232°C

  • Detection Threshold : Donnée indisponible.

  • Optical rotation : Donnée indisponible

  • Vapor pressure : Donnée indisponible

  • Refractive Index @20°C : Donnée indisponible

  • Acid Value : Donnée indisponible.

  • Flash Point : 95°C

Utilisation

Uses

Uses in perfumery :

Trans-2-cis-6-Nonadienol is used to make artificial violet leaf notes and in woody perfumes. It can also be useful to bring a strong mimosa top note. This molecule is used in very low quantity as it is very powerful, and it is diluted before usage.

Year of discovery :

Data not available.

Natural availability :

Trans-2-cis-6-Nonadienol is found on a natural state in Violet Leaf Absolute, and is partly responsible for its green and fatty smell. It can thus be extracted from it.

Isomerism :

The different diastereoisomers of Trans-2-cis-6-Nonadienol can be used in perfumery as they also have a green smell reminiscent of violet leaf and cucumber. They remain much less used than the first compound.

Synthesis precursor :

Trans-2-cis-6-Nonadienol can be used to synthesize its corresponding esters. For example, Trans-2-cis-6-Nonadienyl acetate has a green, fatty and nutty smell.

Synthesis route :

Trans-2-cis-6-Nonadienol is synthesized starting from cis-3-Hexenol, converted into cis-3-hexenyl chloride first, and then blending this product with pure magnesium to form a Grignard reagent. This reagent will undergo a reaction with acrolein, to form nonadien-3-ol, then converted into trans-2-cis-6-nonadienol thanks to an allylic rearrangement.

Utilisation

Regulations & IFRA

Allergens :

This ingredient does not contain any allergen.

IFRA 51th :

This ingredient is not restricted for the 51th amendment

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