Photo credits: ScenTree SAS
Company | Ingredient Name | ID | Naturality | Purity | Latin name | Treated part | Geographical origin | Certifications | Comments | MOQ |
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Lyral® - 30gr | - | - | - | - | - | - | more | - |
General Presentation
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CAS N° : : 31906-04-4
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EINECS number : 250-863-4
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FEMA number : Donnée indisponible.
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Density : 0,995
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Optical rotation : Lorem Ipsum
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Allergens : This ingredient does not contain any allergen.
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Refractive Index @20°C : Lorem Ipsum
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Volatility : Heart
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Price Range : €€
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Appearance : Colorless liquid that crystallizes at room temperature
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FLAVIS number : Donnée indisponible.
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JECFA number : Donnée indisponible.
Information on synthetic ingredients
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Acid Value : Lorem Ipsum
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Boiling Point : 121°C
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Detection Threshold : 0,1 ng/l air
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Molecular formula : C13H22O2
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Log P : 2,08
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Molecular Weight : 210,32 g/mol
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Fusion Point : -20°C
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Flash Point : 105°C
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Vapor pressure : Lorem Ipsum
Uses
Other comments :
Lyral® was subject to a recall procedure in 2019, and its use will be banned in 2021.
It is one of the 26 allergens in perfumery.
Stability :
Aldehydes may form diethylacetals in alcoholic perfumes, with no real impact on their smell.
Uses in perfumery :
Lyral® is used in floral notes such as white flowers, lily of the valley, lilac or lily.
Year of discovery :
Discovered in 1958. Patent N°868,850 published on May 8, 1958 by IFF
Isomerism :
The positional isomer that is formed during the synthesis of Lyral® has no great olfactory difference with Lyral® used in perfumery. Geranyl Propionate is a constitutional isomer of Lyral®. Their smell is very different as Geranyl Propionate is much rosier.
Synthesis precursor :
Lyral® forms Schiff bases in the presence of amino compounds such as Methyl Anthranilate or Indole.
Natural availability :
Lyral® is not available in its natural state.
Synthesis route :
Lyral® is synthesized by a Diels-Alder reaction between Myrcenol and Acrolein (or Propenal) in the presence of a Lewis catalyst such as zinc chloride. When this reaction is performed without a catalyst and at a high temperature, it results in the formation of a mixture of two positional isomers of Lyral®, although Lyral® is still predominant (70%).
Regulations & IFRA
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IFRA 51th : This ingredient is restricted by IFRA
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Restriction type : RESTRICTION
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Cause of restriction : DERMAL SENSITIZATION AND SYSTEMIC TOXICITY
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Amendment : 49
- Quantitative limit on the use :
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Cat.1 Cat.2 Cat.3 Cat.4 Cat.5A Cat.5B Cat.5C Cat.5D Cat.6 0,02 % 0,02 % 0,1 % 0,2 % 0,2 % 0,2 % 0,2 % 0,067 % 0,2 % Cat.7A Cat.7B Cat.8 Cat.9 Cat.10A Cat.10B Cat.11A Cat.11B Cat.12 0,02 % 0,02 % 0,067 % 0,2 % 0,2 % 0,2 % 0,067 % 0,067 % 91 %
Comments :
The restrictions as given for the individual categories are not based on the Quantitative Risk Assessment (QRA) methodology but solely represent a pragmatic approach to address the specific situation for 3 and 4-(4-Hydroxy-4-methylpentyl)-3-cyclohexene-1-carboxaldehyde (HMPCC). This ingredient is part of the Schiff base (Lyral-methyl anthranilate (or Lyrantion) - N°CAS :67634-12-2) and induces the application of IFRA regulations for 61,3% of the Schiff base usage. Please also refer to the IFRA Annex II for more information