Anisic aldehyde

Other comments :

Anisic Aldehyde was used for the first time in perfumery in Après l'Ondée, by Guerlain, in 1906.
Anisic aldehyde is more vanillic than Anisyl Alcohol and less fruity than Anisyl acetate.

Stability :

Aldehydes may form diethylacetals in alcoholic perfumes, with no real impact on their smell
Most of the time, the occurrence of a benzenic cycle in a molecule causes a coloration of this molecule through time

Uses in perfumery :

Anisic Aldehyde is used in lilac and mimosa accords, for a sweet vegetable, aromatic and anisic note.

Year of discovery :

Anisaldehyde was discovered in 1895 by scientist Auguste Cahours, by oxydation of an anise oil.

Isomerism :

The isomer used here is para-Anisic Aldehyde. The ortho and meta isomers have a relatively similar smell. Methyl Benzoate and Phenylacetic Acid are constitutional isomers of Anisaldehyde. Their smell is however very different.

Synthesis precursor :

Anisic Aldehyde is the precursor for the synthesis of Anisic Alcohol by hydrogenation and Anisic Acid by oxidation. It can also react with Methyl Anthranilate or Indole to form a Schiff base.

Natural availability :

Anisic Aldehyde is present in Star Anise EO, Anise EO and Ceylon Cinnamon EO (and other origins), from which it can be extracted.

Synthesis route :

Its synthesis is made by an oxidation from para-Cresol methyl ether, in the presence of manganese dioxide, air or peroxidised compounds (the catalysis of these reactions is metallic). Other routes exist, such as the two-step synthesis from para-Cresol, via 4-hydroxybenzaldehyde, which is then oxidized. A last synthesis route is an electrochemical oxidation in the presence of an aliphatic alcohol. The intermediate product of this route is acetal, corresponding to Anisic Aldehyde.